3 Types of Polyurethane Curing Agents

1st December 2023
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Doxu supplies a comprehensive range of  polyurethane curing agents for various industries. Click and check the detailed specifications.

Polyurethane curing agents typically refer to the components containing isocyanate groups (NCO) in two-component polyurethane products, mainly used in combination with active hydrogen. Common components with active hydrogen include polyether polyols, polyester polyols, epoxy resins, hydroxypropyl acrylic resin, etc. In these products, the addition of curing agents not only increases the crosslinking and cohesion of the products but also enhances the strength, weather resistance, and other properties of the final products. Currently, polyurethane curing agents are widely used in adhesives, coatings, inks, and other fields.

Generally, polyurethane curing agents can be categorized into three main types: solvent-based, water-dispersible, and blocked polyisocyanates.

1. Solvent-Based Polyurethane Curing Agents

Solvent-based curing agents are the most common in the applications, offering enhanced strength, weather resistance, and mechanical properties to the cured materials. It is consisted of polyisocyanates and solvents. The isocyanates within the solvent-based curing agents react with components containing active hydrogen, such as polyols and resins,  to form a durable and crosslinked polyurethane network.

The inclusion of solvents in this type of curing agent facilitates the application and processing of the mixture, ensuring uniform coverage and penetration into substrates. Moreover, solvent-based systems contribute to the enhancement of various material properties, including improved adhesion, flexibility, and resistance to external environmental factors.

Solvents

Solvents used in polyurethane curing agents include Acetic ethyl ketone, butyl acetate, propylene glycol monomethyl ether acetate, acetone, toluene, mixed xylene, dichloromethane, and others. It depends on various factors to decide which solvent is suitable for the application including chemical compatibility with other components, volatility for drying time, viscosity.

Solvents play a crucial role in the curing agents, especially in solvent-based formulations. Generally, the main goal of using solvents is to reduce the viscosity for ease of application during construction. Rather than that, solvents help facilitate the dissolution and dispersion of isocyanates, promoting their effective reaction with hydroxy, such as polyols and resins. The addition of solvents also contributes to the enhanced properties of cured polyurethane products including improved adhesion, flexibility.

Components of solvent-based polyisocyanate curing agents

 

2. Waterborne Polyurethane Curing Agents

With the growing emphasis on environmental awareness, waterborne polyurethane materials have gained increasing attention. In two-component waterborne polyurethane products, the isocyanate component plays a crucial role. A common practice involves hydrophilic modification of isocyanates to achieve dispersion in water. The primary methods of modification include non-ionic modification, anionic modification.

Non-ionic hydrophilic

Non-ionic modification involves the use of hydrophilic substances such as polyethylene glycol monomethyl ether (MPEG) and polyethylene glycol (PEG) to chemically modify polyisocyanates. The resulting modified polyurethane curing agent not only exhibits a certain degree of hydrophilicity but also encapsulates the residual isocyanate groups (NCO groups), enabling them to remain stable in water for a period of time. This modification contributes to the preparation of waterborne polyurethane products by ensuring the uniform dispersion of polyisocyanates in water and maintaining stability for a specified duration.

Components of  Non-ionic Hydrophilic Curing Agents

Doxu WD-9100 Non-ionic Hydrophilic PU Hardener

Type Non-ionic Hydrophilic
Appearance Colorless to pale yellow transparent viscous liquid
COLOR (Pt-Co) ≤100
NCO % 18±0.5
Free Monomer % HDI≤0.2
Solid Content% 100
Viscosity/ /25℃  (CPS) 2500±1000

 

Anionic hydrophilic

Hydrophilic polyisocyanates can also be obtained through ionic modification. Common ionic modifications include carboxylate modification and sulfonate modification. Carboxylate modification typically involves using dimethylolpropionic acid (DMPA), while sulfonate modification generally utilizes ethylenediamine-based sulfonic acid salts and amino sulfonic acid salts. These compounds introduce carboxyl or sulfonic acid groups onto the molecular chain, allowing the polyurethane curing agent to emulsify in water.

Components of  Aionic Hydrophilic Curing Agents

 

Doxu Anionic Hydrophilic PU Hardeners

Product WD-8100 WD-8300 WD-8300-1 WD-8400
Type Anionic Hydrophilic Anionic Hydrophilic Anionic Hydrophilic Anionic Hydrophilic
Appearance Colorless to pale yellow transparent viscous liquid Colorless to pale yellow transparent viscous liquid Colorless to pale yellow transparent viscous liquid Colorless to pale yellow transparent viscous liquid
COLOR (Pt-Co) ≤100 ≤100 ≤100 ≤100
NCO % 20.5 ± 0.5 21.5 ± 0.5 21±0.5 18±0.5
Free Monomer % HDI≤0.3 HDI ≤0.3 HDI≤0.3 HDI ≤0.3
Solid Content% 100 100 100 ≥97.5
Viscosity/ /25℃  (CPS) 4500 ± 500 1500 ± 500 4800±1000 2000±1000

3. Blocked Polyurethane Curing Agents

The NCO groups in the curing agent component exhibit high reactivity and can react with atmospheric moisture at room temperature, leading to degradation. To facilitate storage and minimize raw material loss, a closed-cell curing agent can be obtained by reacting a blocking agent with NCO, resulting in a stable curing agent at room temperature.

Upon heating, the closed-cell curing agent can revert to its original isocyanate structure and react with components containing hydroxyl groups. The formulation strategy typically involves introducing a blocking agent into common solvent-based and water-dispersible polyurethane curing agents, effectively capping excess NCO groups. Different blocking agents exhibit varying unblocking temperatures, allowing for tailored selection based on specific usage scenarios. Common blocking agents and their unblocking temperatures are detailed in the table below:

Blocking Agent Unblocking Temperature/℃
Caprolactam 175-200
Ethanol 180-185
Methyl ethyl ketoxime 140-150
Phenol 140-145
Acetoxime 130-140
Ethyl acetoacetate 125-150

Blocked polyisocyanate curing agents are commonly used in can&coil coatings. Curing occurs after heating up to the activation temperature, which forms a durable and stable structure with improved toughness, wear and scratch resistance.

can-and-coil-coating

Doxu Blocked Polyisocyanate PU Hardeners

Product DXTB-65 DXB-75 C/D/E DXB-3465 BI-40 C/D/E BI-70 C/D/E
Type Solvent-Based TDI Blocked Solvent-Based HDI Blocked Solvent-Based IPDI Blocked Water-dispersive HDI Blocked Water-dispersive HDI Blocked
Appearance Colorless to pale yellow transparent viscous liquid Colorless to pale yellow transparent viscous liquid Colorless to pale yellow transparent viscous liquid Colorless to pale yellow transparent viscous liquid Colorless to pale yellow transparent viscous liquid
Solid Content% 65±2 75±2 65±2 40±2 70±2
Valid NCO % 8±0.3 11.2±0.5 7.5±0.5 4.1±0.5 10±0.5
Free Monomer % ≤0.2 ≤0.2 ≤0.2 ≤0.2 ≤0.2
Viscosity/ /25℃  (CPS) 8000±2000 3000±1000 800±300 150-500 5000±2000
Deblocking Temp. ℃ 130-140 120 / 130 / 150 130-140 120 / 130 / 150 120 / 130 / 150
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